xmlns:xsi XML Schema Namespace Declaration

This is not an attribute, but the namespace pseudo-attribute. The value provides a prefix to use in namespace pseudo-attributes such as @xsi:noNamespaceSchemaLocation. All namespace prefixes must be associated with a URL, and the prefix “xsi” has been set to the URL for the World Wide Web Consortium (W3C) XML Schema.
FIXED (not settable) on many elements; click for list and usage
Value Meaning
http://www.w3.org/2001/XMLSchema-instance The prefix “xsi” has been set to the URL for W3C XML Schema.
Restriction @xmlns:xsi has a fixed value which may not be changed in the document.
Tagged Sample

The @xmlns:xsi namespace for an entire book

<book
  xmlns:mml="http://www.w3.org/1998/Math/MathML"
  xmlns:xi="http://www.w3.org/2001/XInclude"
  xmlns:xlink="http://www.w3.org/1999/xlink"
  xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
  book-type="gov"
  dtd-version="2.1"
  indexed="yes"
  xml:lang="en">
 <book-meta>...</book-meta>
 <book-body>...</book-body>
 <book-back>...</book-back>
</book>